To use the Discord Overlay in any game, you have to enable it in the Discord app settings first. If You are Facing: Fix Reboot and Select Proper Boot Device Method #2 Check If The Option Is Enabled Fire it up again, keeping the fingers crossed, and see if this fixed the Discord overlay not working.
Just close all running games, applications and discord app and shut down the machine. However silly this seems, this is known to be a magical fix for many problems and, you never know, might even fix the issue! Reboot computer
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